It has two lone pairs (4 electrons) and a double bond (2 electrons). Include all lone pairs of electrons. The formula for calculating the formal charge of an atom is. 58 people found it helpful. Chemistry questions and answers. For the ClO2 - resonanc. Do not alter the structure‑just add charges. In this section, we will explore the formal charge of BH3 (boron hydride) and how it is calculated. Now, you have come to the final step and here you have to check the formal charge on chlorine atom (Cl), oxygen atoms (O) as well as hydrogen atoms (H). Oxygen = 6 – 6 – 2/2 = -1. Both methanol and ethanol produce CO 2 and H 2 O when they burn. POCl3 , ClO4, SO2 Cl2, ClO3^-, SO4, PO4^3 , XeO4, NO4^-3. ClO4− Draw the molecule by placing atoms on the grid and connecting them with bonds. We start with a valid Lewis structure and then follow these general rules. There are another three oxygen atoms. Additional information:. There are 3 steps to solve this one. The high electronegativity of Cl makes this separation of charge unlikely and suggests that this is not the most important resonance structure for BCl 3. There are 4 steps to solve this one. It is also proved that the molecule is neutral in nature so no formal charge over it. View Solution. Formal charges can be used as guidelines to determine the plausibility of Lewis structures by comparing the stability of non-equivalent resonance structures, which is particularly important for organic species. Cl: 7 – 7 = 0. formal charge = number of valence electrons − (number of nonbonding electrons + 1/2 number of bonding electrons) A. By assigning formal charges, we can determine the most stable resonance structure with an average bond order of 1. ClO4 Draw the molecule by placing atoms on the grid and conne View Available Hint (s)ClO4− Draw the molecule by placing atoms on the grid and connecting them with bonds. May 26, 2023 · Hence the charge of ClO in NaClO is 1-. NO3− ClO4− ClO3−. You'll want to calculate the formal charges on each atom to make sure you have the best Lewis structure for ClO 4-. & Formal\text{ }charge\,of\,\sec ond,\,third\,and\,fourth\,oxygen=6-4-\dfrac{4}{2}=0 \\ \end{align}\] So, effective charge on oxygen will become -0. Correlation (Literature values of bond-distances of some oxide based acid radicals with their predicted bond order values) Literature values of the Cl-O average bond lengths in ClO 4-,ClO 3-and ClO 2-; As-O bond lengths in AsO 4 3-and AsO 3 3 - with respect to their bond order values suggest that with increasing bond-order M-O bond. x = + 1. When we drew the lewis structure, overall charge of the ion should be -1. 4 days ago · Hint: To solve these types of questions we should first draw the Lewis structure. If you need to revert the drawing palette to the original state, select the More menu, then select Reset Drawing. Question: In the following Lewis structure for ClO3F, chlorine has a formal charge of ____ and an oxidation number of ____. Step 1 of 3. Lewis structure having maximum number of formal charge is zero will be the most stable configuration. In order to draw the lewis structure of ClO4 - ion, first of all you have to find the total number of valence electrons present in the ClO4 - ion. Each hydrogen atom (group 1) has one valence electron, carbon (group 14) has 4 valence electrons, and oxygen (group 16) has 6 valence electrons, for a total of [ (2) (1) + 4 + 6] = 12 valence electrons. Draw a Lewis structure that obeys the octet rule for each of the following ions. This -1 negative charge is located at an oxygen atom. This species has its three atoms bonded sequentially in the following fashion: N. 5*2 – 6 = 6 – 1 – 6 = -1. As the total formal charge distribution on the hypochlorite molecule is -1, the aforementioned Lewis structure withholds most stability and credibility. Distribute the remaining electrons as lone pairs on the terminal atoms (except hydrogen), completing an octet around each atom. Apr 22, 2023 · The formal charge of each atom in a molecule can be calculated using the following equation: Formal Charge = (# of valence electrons in free atom) - (# of lone-pair electrons) - (1/2 # of bond pair electrons) Eqn. CO32− c. Draw the molecule by placing atoms on the grid and connecting them with bonds. ) ClO4−. Byju's Answer Standard XII Chemistry Millikan's Oil Drop Experiment 36. The material itself is noncombustible, but it can form a very flammable mixture with combustible materials, and this mixture may be explosive if the. Assign the formal charge for the. Often, many Lewis dot structures are possible. A step-by-step explanation of how to draw the ClO4- Lewis Structure (Perchlorate Ion). Assign formal charges to each atom. Sodium perchlorate is an inorganic sodium salt comprising equal numbers of sodium and perchlorate ions. BM Brandon M. Show the formal charges of all nonhydrogen atoms. C N − CN^-C N − c. Assign the formal charge for the central atom of XeO4. The oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds. Formal charge is the individual electric charges on the atoms in a given polyatomic molecule. Step 3. Therefore shape of the anion around chlorine atom is tetrahedral. As we can see, the molecule's centre atom carries a -1 charge, which is the charge that the entire structure is carrying. Now, let's determine the formal charges of each atom in the molecule to see if the structure above is the most stable one. For the central carbon atom. View Solution. Lewis Structure of ClO. So, the formal charge on Cl in HClO 4 is. Question: A student proposes the following Lewis structure for the peroxide (O2 ) ion. It contains a perchlorate. If the three O were single bonded, then Cl would have had a formal charge. Question: BrO2- Draw the molecule by placing atoms on the grid and connecting them with bonds. ClO^- ClO− d. c) What is the formal charge on each oxygen atom in oxalate ion? Formal charge on oxygen = (-1 + 0 + (-1) + 0)/4 = -1/2 3. If you need to revert the drawing palette to the original state, select the More menu, then select. Step-by-step solution: 92 % ( 25 ratings) for this solution. ClO4− Draw the molecule by placing atoms on the grid and connecting them with bonds. Cl: 7 – 7 = 0. Verified by Toppr. Oct 22, 2019 · By assigning formal charges, we can determine the most stable resonance structure with an average bond order of 1. Chlorate ion (ClO4-) is a polyatomic ion that consists of one central chlorine atom surrounded by four oxygen atoms. But more on that later!. Include resonance structures if necessary and assign formal charges to each atom. 2) Draw a Lewis diagram for ClO4- in which the central Cl atom has a formal charge of zero and show all NONZERO formal charges on all. When we do this, you should be careful to protect stability of ion, octal rule and more. The formal charges work out as follows: For the arrangement HNC, the Lewis structure: H-N\(\equiv\)C: The formal charges work out as follows: Both Lewis structures have a net formal charge of zero, but note that the formal charges on the first structure are all zero! Thus the first Lewis structure is predicted to be more stable, and it is, in. The net charge on the species is +1. (diacetylene may be a little tricky!) Answer. The bond angle in ClO2- is slightly less than 109°. The resonance hybrid of the perchlorate ion, ClO4-, is described by 16 resonance structures, a representative subset of which is shown. The central Cl atom forms __ double bonds. to balance the charges, Mo has to be +5. Formal charge of an atom = (Valence electrons - No. Lewis structure having maximum number of formal charge is zero will be the most stable configuration. Formal charge is the individual electric charges on the atoms in a given polyatomic molecule. Determine the formal charge on the chlorine atom in the hypochrlorite ion ClO-, and the perchlorate ion, ClO4- if the Cl atom has an octet. Assign formal charges to each atom. The formal charge on any atom in a Lewis structure is a number assigned to it according to the number of valence electrons of the atom and the number of electrons around it. In HClO, the ClO is bonded to Hydrogen (H). Exercise 2. If the three O were single bonded, then Cl would. Connect each atom to the central atom with a single bond (one electron pair). Write a Lewis structure that obeys the octet rule for each ion. This is based on comparing the structure with. For that, you need to remember the formula of formal charge;. A perchlorate is a chemical compound containing the perchlorate ion, ClO 4−, the conjugate base of perchloric acid ( ionic perchlorate ). If you need to revert the drawing palette to the original state, select the More menu, then select. We can convert each lone pair to a bonding electron pair, which gives each atom an octet of electrons and a formal charge of 0, by making three C=C double bonds. Formal charge = valence electrons – No. The formal charge of an atom is equal to the number of valence electrons, N v. Include resonance structures if necessary andassign formal charges to each atom. For each of the O in a single bond with carbon, formal charge = 6 – 0. (b) What are the oxidation numbers of chlorine in ClO- and in ClO4-? (c) Is it uncommon for the formal charge and the oxidation state to be different? Explain. Three carbon atoms now have an octet configuration and a formal charge of −1, while three carbon atoms have only 6 electrons and a formal charge of +1. Draw the molecule by placing atoms on the grid and connecting them with bonds. This conclusion is shown to be valid based on the three equivalent B. Sodium perchlorate melts with decomposition at 480. For, Chlorine = 7 – 6 – 2/2 = 0. POCl3 , ClO4, SO2 Cl2, ClO3^-, SO4, PO4^3 , XeO4, NO4^-3. of electrons – No. Question: Based on the Lewis dot structure of : ClO4- Determine the following for the central atom: Bonding regions: Nonbonding regions: Formal charge: Formal charges should be entered as sign then number without a space, like -1,+1, 0. Assign the formal charge for each central. The perchlorate ion, ClO4-, is a main componentof rocket propellants. If you need to revert the drawing palette to the original state, select the More menu, then select. Assign formal charges to each atom. It is a conjugate acid of a perchlorate. SeO_2 SeO2 b. Formal charge = valence electrons – No. Place all remaining electrons on the central atom. Now, you have come to the final step and here you have to check the formal charge on bromine atom (Br), oxygen atoms (O) as well as hydrogen atoms (H). It is also proved that the molecule is neutral in nature so no formal charge over it. By using the following steps, you can easily draw the Lewis structure of ClO 4 -: #1 Draw skeleton #2 Show chemical bond #3 Mark lone pairs #4 Calculate formal charge and check stability (if octet is already completed on central atom) #5 Convert lone pair and calculate formal charge again (if formal charges are not closer to zero). Covalent Lewis Structures, Resonance, and Formal Charge 64. For example, in ClO4-, three O are double bonded with the Cl so that the Cl has a formal charge of zero. Draw the molecule, with the correct chirality, by placing atoms on the grid and connecting them with bonds. In order to calculate the formal charges for PO43-- we'll use the equationFormal charge = [# of valence electrons] - [nonbonding val electrons] - [bonding. Monoisotopic mass 98. For example, in ClO4-, three O are double bonded with the Cl so that the Cl has a formal charge of zero. Write a Lewis structure that obeys the octet rule for each molecule or ion. Clearly, the negatuve charge is localized on oxygen in this representation, but all the oxygen atoms are formally equivalent. Electrochemistry 1h 38m. Electronegative ligands such as F will always go to. appears as crystalline or powdered solids. Show the formal charges of all atoms in the correct structure. Use formal charge to select which resonance structure makes the largest contribution to the resonance hybrid. There are 4 steps to solve this one. You'll get a detailed solution from a subject matter expert that helps you learn core concepts. May 23, 2023 · Step #6: Final step – Check the stability of lewis structure by calculating the formal charge on each atom. Draw its Lewis structure. Given a static resonance structure, all of the atoms are neutral, save ONE negatively charged oxygen. ClO3- b. Consider the resonance structures for #"O"_3#. Nov 13, 2023 · Steps. #4 Minimize formal charges by converting lone pairs of the atoms, and try to get a stable Lewis structure. ClO4 is polar. Calculate the formal charge on atoms in carbonate ion. For each of the following molecules or ions of sulfur and oxygen, write a single Lewis structure that obeys the octet rule, and calculate the oxidation numbers and formal charges on all the atoms: (c) SO32- Write a single Lewis structure that obeys the octet rule for SO3 2 - and assign the formal charges on all the atoms. Step #1: Calculate the total number of valence electrons. The number of valence electrons formally assigned to each atom is then compared with the number of valence. Question: 61. Assign formal charges to each atom. Remember to put brackets around the Lewis structure, along with a negative sign, to show that it is. Formal charge of an atom = (Valence electrons – No. For the oxygen: 6−4− 1 2×4 =0. In ClO2- lewis dot structure, the total number of 7 lone pairs and 3 bond pairs are present. Subtract the number of bonding electrons from the total. Valence electrons of carbon = It is present in Group IV A = 4 valence electrons. Even though a double bond contains 4 electrons total and is counted as such when seeing. Include resonance structures if necessary and assign formal charges to each atom. The sum of the formal charges in a molecule or ion must equal the overall charge on the species. For example: ZnCl4 {2-} or NH2NH3 {+}. Answer : Valence electron of Cl = 7 Formula for farmal charge : Valence electon - non bonding electron - 1/2 ( bond pair electron) Formal charge on chlorine atom in ClO- 7 - 6 - 1/2 ( 2) 0 Formal charge on Chlorine. NO3− Draw the molecule by placing atoms on the grid and connecting them with bonds. SeO2 b. Of course the negative charged is distributed over all the oxygen centres by resonance. Place all remaining electrons on the central atom. Formal charge = valence electrons – No. Bonding electrons = 3 single bonds = 3 (2) = 6 electrons. The smaller the difference, the “happier” (more stable) the atom is. Write the chemical equations for these combustion reactions using Lewis structures instead of chemical formulas. SO2Cl2 f. It is impossible to draw a legitimate Lewis structure of a neutral NH4 molecule. You know that the ionic charge of K is 1+. ) NH4+ please only answer if you know how to do it, i've tried many combinations on all 4 parts and can't get it right, please help!!. The formal charge on an atom is calculated by the following formula:. Perchloric acid is a chlorine oxoacid. In order to calculate the formal charges for ClO4- we'll use the equation: Formal charge = [# of valence electrons] - [nonbonding val electrons] - [bonding electrons / 2] The number of. If the three O were single bonded, then Cl would have had a formal charge. If we then examine the structure as it is, we can see that the chlorine atom has a negative charge linked to it, as is evident from the image that is attached to the question. Nov 30, 2011 · In this problem we have ClO 4-. You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Nov 13, 2023 · Here’s how you can easily draw the HClO 4 Lewis structure step by step: #1 Draw a rough skeleton structure. Show the formal charges of all atoms in the correct structure. Draw the molecule by placing atoms on the grid and connecting them with bonds. Formal charge in one oxygen with single bond = 6-6-1 = -1 The formal charge of atoms in chlorate anion is zero for two chlorine and two oxygen atoms. Show the formal charges of all atoms in the correct structure. POCl3 , ClO4, SO2 Cl2, ClO3^-, SO4, PO4^3 , XeO4, NO4^-3. P O 4 3 − PO_4^{3-} P O 4 3 − b. In KClO 4, the ClO 4 is bonded to Potassium (K). How to Calculate the Formal Charges for ClO- (Hypochlorite ion)In order to calculate the formal charges for ClO- we'll use the equation:Formal charge = [# of. BH3 Lewis Structure Formal Charge. A commonly used perchlorate is ammonium perchlorate (NH 4 ClO 4) found in solid rocket fuel. Oxygen = 6 – 6 – 2/2 = -1. XeO4 c. - Charge. Draw the Lewis dot structure for (CH3)4NCl. Nov 13, 2023 · Steps. Step #1: Calculate the total number of valence electrons. Closed containers may rupture violently under prolonged exposure to heat. All unshared valence electrons are shown. Formal charge = Total number of valance electrons – number of electrons remain as nonbonded – (number of electrons involved in bond. Obeying the octet rule may mean that the structure you draw is not the most stable or ideal for the given molecule. For the oxygen: 6−4− 1 2×4 =0. Formal charge is the individual electric charges on the atoms in a given polyatomic molecule. ∴ The formal charge on the central C-atom in CH3 is 0. Write a Lewis structure that obeys the octet rule for each molecule or ion. Step 1: Find the total valence electrons in ClO4- ion In order to find the total valence electrons in ClO4- ion (perchlorate ion), first of all you should know the valence electrons present in chlorine atom as well as oxygen atom. Formal change on the oxygen atom which has an electron pair shared by chlorine and another by the. Now, let’s take a closer look at each step mentioned above. Question: Draw the Lewis structure for the perchlorate ion (ClO4) with minimized formal charges. Note that you should put the ClF4 - Lewis Structure in bra. The formal charges can be calculated using the formula given below: The formal charge of an atom = [valence electrons of an atom – non-bonding electrons – ½ (bonding electrons)] The valence electrons (V. PROBLEM 3. Let formal charge of Cl in C l O 3 − be x. Monoisotopic mass 98. Question: Draw the best Lewis Structure for ClO4– based on overall formal charges. Step #6: Final step – Check the stability of lewis structure by calculating the formal charge on each atom. 1 7. For the POCl3 structure use the periodic table to find the tota. Step #1: Calculate the total number of valence electrons. For each of the O in a single bond with carbon, formal charge = 6 – 0. Write the chemical equations for these combustion reactions using Lewis structures instead of chemical formulas. The structure with the least amount of formal charges or those. Here are the formal charges for N2O4: Each oxygen atom (O) has a formal charge of 0. sac nuru
Valence electrons in Chlorate anion, ClO 3 –. . Clo4 formal charge
Explanation: 1) To add formal charges to the incomplete structure of ClO4, we need to determine the number of valence electrons each atom should have. NO2− 62. Draw three resonance structures for N3-. It comprises a chlorine atom which is bonded to four atoms of oxygen. The formal charge is a concept used in chemistry to determine the distribution of electrons in a molecule or ion. Formal charge on the carbon atom = 4– 1 – 6/2 = 4– 1 – 3= 4 – 4 = 0. Science Chemistry Draw a Lewis structure that obeys the octet rule for each of the following ions. Formal charge: Formal charges should be entered as sign then number without a space, like -1,+1,0. Draw the molecule by placing atoms on the grid and connecting them with bonds. Corrosive to metals and tissue. This is a hypothetical measure, not a real representation of the actual charge on an atom, which looks at the ways electrons are actually shared between atoms in a bond. Here’s the best way to solve it. Click here to see a video of. Include resonance structures if necessary, and assign formal charges to each atom. Draw a Lewis structure for Cl_2O_7 with the lowest formal charges and predict any deviation from the ideal for the Cl-O-Cl bond angle. x = + 1. To draw a Lewis structure of a compound, we have to first determine the total valence electrons in the compound. Assign the formal charge for the. Standard XII. Explanation: The perchlorate ion (ClO4-) can be represented using multiple Lewis structures, also known as resonance forms. Calculate the formal charge on the nitrogen atom in N H+ 4. So to find the oxidation number of Cl we can write what i just said in to a formula of: (the number of first atoms) (the oxidation number the first atom) + (the. A commonly used perchlorate is ammonium perchlorate (NH 4 ClO 4) found in solid rocket fuel. In this section, we will explore the formal charge of BH3 (boron hydride) and how it is calculated. To calculate the formal charge, take the number of valence electrons in the free atom, subtract the electrons assigned to the atom in the Lewis structure (counting each. How many double bonds are there in the structure that you have drawn?number of double bonds = ___01234Draw a Lewis diagram in which the octet rule is satisfied on all atoms. NH4 +. atom formal charge X 5 ? CI top 0 6000 right o bottom o. Polarity of the O−H O − H bond in HClOX4 H C l O X 4 is guaranteed via. There are 2 steps to solve this one. This resonance stabilization dominates the Lewis structure over simply drawing four double bonds to chlorine. It is a conjugate acid of a perchlorate. ClO^- ClO− d. To determine the formal charge of each atom in N2O4, we need to calculate the formal charge using the formula mentioned earlier. Now, let's determine the formal charges of each atom in the molecule to see if the structure above is the most stable one. ) on an atom in a Lewis structure=. Question: 1. Place all remaining electrons on the central atom. Studying the formal charge distribution in detail also gives us the reason behind the double bond forming between one. What is the formal charge on the central chlorine atom in the molecular ion [ClO4]- ? Assume that all of the Cl-O bonds are single bonds. This is because each perchlorate ion (ClO4^-) has a charge of -1, and there are three of them in the structure. Finally, to satisfy the octet rule, we need to form double bonds between Cl and three of the O atoms. 1 7. A step-by-step explanation of how to draw the ClO4- Lewis Structure (Perchlorate Ion). Given a static resonance structure, all of the atoms are neutral, save ONE negatively charged oxygen. POCl3 , ClO4, SO2 Cl2, ClO3^-, SO4, PO4^3 , XeO4, NO4^-3. Assign formal charges to each atom. Textbook Question. Thus the clo- lewis structure is. 3% fluorine by mass, and determine the formal charge of the atoms in this compound. To calculate the formal charge in chemistry subject, students can use the following formula Formal Charge = [Number of valence electrons on atom] – [non-bonded electrons + number of bonds]. Show the formal charges of all atoms in the correct structure. Assign formal charges to each atom. And so, in this case, because phosphorus and its atomic form has five valence electrons and we only have four valence electrons here, the central atom has a positive one charge. Hence the stable structure of HClO 4 is given below: The formula charge of the Cl atom for the new structure is = 7 − 0 − 1 2 ( 14) = 0. Finding out the formal charge of the central atom should tell you whether or not the element will follow the octet guideline, given that the element is in Periods 3+. (Valence electrons are the number of electrons present in the outermost shell of an atom). This resonance stabilization dominates the Lewis structure over simply drawing four double bonds to chlorine. For this exercise, we are going to determine the formal charge of the chlorine atom in the given polyatomic ion. In the H2TeO4 molecule, the Te atom is the central atom. Thanks for breaking down the Lewis structures and formal charges for the ions, Rahel! Really helped me understand it. nitric oxide has. Molecular Formula ClO. N2O4 Lewis Structure Formal Charge. The formal charge of chlorine and oxygen while in the bond must be calculated to determine the charge of hypochlorite. Lone pairs, charges and bonds of ClO 4- ion lewis structure. NO3− ClO4− ClO3−. There are four oxygen atoms in SO 42- ion, Therefore. It comprises a chlorine atom which is bonded to four atoms of oxygen. Obeying the octet rule may mean that the structure you draw is not the most stable or ideal for the given molecule. Subtract this number from the number of valence electrons for the neutral atom: I: 7 – 8 = –1. Formal Charge. To draw a Lewis structure of a compound, we have to first determine the total valence electrons in the compound. To illustrate this method, let’s calculate the formal charge on the atoms in ammonia (NH 3) whose Lewis structure is as. Assign formal charges to each atom. Show the formal charges of all nonhydrogen atoms. Draw the Lewis structure with a formal charge C_2H_2Br_2. Assign the formal charge for the central atom of XeO4. How many TOTAL equivalent likely resonance structures exist for ClO4 ?. Question: ClO4 - ClO3 - NO3 - NH4 +. Formal change: The formal change of an atom (polyatomic) in a. (Valence electrons are the electrons that are present in the outermost orbit of any atom. C N − CN^-C N − c. Draw a Lewis structure that obeys the octet rule for each of the following ions. Question: Draw the Lewis structure for the perchlorate ion (ClO4−)with minimized formal charges. Formal charge in oxygen = 6-4-2 = 0. Using Equation 8. Since each bond takes 2 electrons, we can calculate and substitute the remaining electrons to the. The drawn structure for ClO 4-is not a stable structure because oxygen atoms and chlorine atoms have charges. Draw the molecule by placing atoms on the grid and connecting them with bonds. The formal charge (F. Include all lone pairs of electrons. Show the formal charges of all atoms in the correct structure. In order to calculate the formal charges for ClO2- we'll use the equation:Formal charge = [# of valence electrons] - [nonbonding val electrons] - [bonding el. Now, you have come to the final step and here you have to check the formal charge on bromine atom (Br), oxygen atoms (O) as well as hydrogen atoms (H). The formal charge of each atom in a molecule can be calculated using the following equation: Formal Charge = (# of valence electrons in free atom) - (# of lone-pair electrons) - (1/2 # of bond pair electrons) Eqn. ClO2- is a polar molecule due to the asymmetrical distribution of charges caused by the presence of lone pair electrons. This problem has been solved! You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Also, when charge of an atom (in chlorine atom, there. N and N. A perchlorate is a chemical compound containing the perchlorate ion, ClO 4−, the conjugate base of perchloric acid ( ionic perchlorate ). +7 for Cl and -2 for O in ClO4- ion. In order to draw the lewis structure of ClO4 - ion, first of all you have to find the total number of valence electrons present in the ClO4 - ion. For each resonance structure, assign formal charges to all atoms that have formal charge. Calculate the formal charge on the central oxygen atom in O3. This is a hypothetical measure, not a real representation of the actual charge on an atom, which looks at the ways electrons are actually shared between atoms in a bond. 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